When you have started the WinPE (this should work starting with WinPE for Windows 7) environment open a command line and start a command prompt. First you need to mount the EFI system partition:
# diskpart
# list disk
# sel disk 0
# list partition
# assign letter=b
# exit
Now the EFI system partition should be as drive
b:
.In the next step you can start to edit you BCD entry:
# bcedit /store b:/efi/microsoft/boot/bcd /enum
# bcedit /store b:/efi/microsoft/boot/bcd /deletevalue {default} safeboot
In this example a safeboot entry would be deleted from the store.